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A: Hydrogen Sulfide is a colorless, transparent gas with a characteristic rotten-egg odor at low concentrations. It is not detectable by odor at high concentrations. As the level of H2S increases, the sense of smell is lost!
Hydrogen Sulfide is a naturally occurring gas mixed with natural gas or dissolved in the oil or brine and released upon exposure to atmospheric conditions.
ACGIH 2008 recommendations are as follows for Threshold Limit Values for H2S:
A Short Term Exposure Limit (STEL) is a TLV(R) based on a 15 minute average.
Short Term Exposure Level - STEL (15 min Average) - 15ppm
Long Term Exposure Level -TWA (8 hr average) - 10ppm
| Exposure Level (ppm) | Physiological Response to H2S: |
|---|---|
| 10 ppm | Beginning eye irritation |
| 50-100 ppm | Slight conjunctivitis (bloodshot eyes) and respiratory tract irritation after 1 hour exposure |
| 100 ppm | Immediately Dangerous to Life and Health. Coughing, eye irritation, loss of sense of smell after 2-15 minutes. Altered respiration, pain in the eyes and drowsiness after 15-30 minutes followed by throat irritation after 1 hour. Death may occur within the next 48 hours. |
| 200-300 ppm | Marked conjunctivitis and respiratory tract irritation after 1 hour of exposure |
| 500-700 ppm | Loss of consciousness and possibly death in 30 minutes to 1 hour |
| 700-1000 ppm | Rapid unconsciousness, cessation of respiration and death |
| 1000-2000 ppm | Unconsciousness at once, with early cessation of respiration and death in a few minutes. Death may occur even if individual is removed to fresh air at once. |